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Tetra-?-acetato-bis-[(pyridine N-oxide)copper(II)](Cu-Cu).

ABSTRACT: The mol-ecule of the title binuclear copper(II) complex, [Cu(2)(CH(3)COO)(4)(C(5)H(5)NO)(2)], occupies a special position on a crystallographic inversion centre; the coordination environment of the Cu(II) atom is slightly distorted square-pyramidal and is made up of four O atoms belonging to four acetate groups in the basal plane with the O atom of pyridine N-oxide ligand in the apical position. The Cu-Cu distance is 2.6376?(6)?Å.

SUBMITTER: Cui Y

PROVIDER: S-EPMC2977355 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Tetra-μ-acetato-bis-[(pyridine N-oxide)copper(II)](Cu-Cu).

Cui Yue Y Gao Qian Q Zhang Chao-Yan CY Xie Ya-Bo YB

Acta crystallographica. Section E, Structure reports online 20090701 Pt 8

The mol-ecule of the title binuclear copper(II) complex, [Cu(2)(CH(3)COO)(4)(C(5)H(5)NO)(2)], occupies a special position on a crystallographic inversion centre; the coordination environment of the Cu(II) atom is slightly distorted square-pyramidal and is made up of four O atoms belonging to four acetate groups in the basal plane with the O atom of pyridine N-oxide ligand in the apical position. The Cu-Cu distance is 2.6376 (6) Å. ...[more]

PMID: 21583319

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