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Tetra-?-acetato-?O:O'-bis-{[2,2-dimeth-yl-N-(pyridin-2-yl)propanamide-?N]copper(II)}(Cu-Cu).

ABSTRACT: The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octa-hedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu-Cu bond. The amide H atom forms intra-molecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak inter-molecular pyridine-amide C-H?O inter-actions are also present.

SUBMITTER: Asem S

PROVIDER: S-EPMC3238774 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Tetra-μ-acetato-κO:O'-bis-{[2,2-dimeth-yl-N-(pyridin-2-yl)propanamide-κN]copper(II)}(Cu-Cu).

Asem Samuel S Buchanan Robert M RM Mashuta Mark S MS

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octa-hedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu-Cu bond. The amide H atom forms intra-molecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak inter-molecular pyridine-amide C-H⋯O inter-actions are als ...[more]

PMID: 22199651

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