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Trans-Dibromidobis(triphenyl-phosphine-?P)palladium(II) chloro-form monosolvate.

ABSTRACT: The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2977421 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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trans-Dibromidobis(triphenyl-phosphine-κP)palladium(II) chloro-form monosolvate.

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis. ...[more]

PMID: 21583391

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