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Dibromidobis(triphenyl-arsine)palladium(II).

ABSTRACT: In the title compound, [PdBr(2)(C(18)H(15)As)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two As atoms [Pd-As = 2.4184?(3)?Å] and two Br anions [Pd-Br = 2.4196?(3)?Å] in a slightly distorted square-planar geometry [As-Pd-Br = 90.12?(1)°]. The crystal packing exhibits weak inter-molecular C-H?Br inter-actions.

SUBMITTER: Kirsten L

PROVIDER: S-EPMC2968301 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Dibromidobis(triphenyl-arsine)palladium(II).

Kirsten Leo L Steyl Gideon G

Acta crystallographica. Section E, Structure reports online 20090123 Pt 2

In the title compound, [PdBr(2)(C(18)H(15)As)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two As atoms [Pd-As = 2.4184 (3) Å] and two Br anions [Pd-Br = 2.4196 (3) Å] in a slightly distorted square-planar geometry [As-Pd-Br = 90.12 (1)°]. The crystal packing exhibits weak inter-molecular C-H⋯Br inter-actions. ...[more]

PMID: 21581811

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