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(2,6-Difluoro-benzophenone)tris-(trimethyl-phosphine)cobalt(0).

ABSTRACT: In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethyl-phosphine ligands and a ?-coordinated carbonyl group of the 2,6-difluoro-benzo-phenone ligand in a distorted tetra-hedral geometry. The Co-O and Co-C distances are 1.896?(2) and 2.049?(4)?Å, respectively.

SUBMITTER: Ding J

PROVIDER: S-EPMC2977559 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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(2,6-Difluoro-benzophenone)tris-(trimethyl-phosphine)cobalt(0).

Ding Jun J Li Xiao-Yan XY

Acta crystallographica. Section E, Structure reports online 20090408 Pt 5

In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethyl-phosphine ligands and a π-coordinated carbonyl group of the 2,6-difluoro-benzo-phenone ligand in a distorted tetra-hedral geometry. The Co-O and Co-C distances are 1.896 (2) and 2.049 (4) Å, respectively. ...[more]

PMID: 21583745

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