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Cyanidotetra-kis-(trimethyl-phosphine)cobalt(I).

ABSTRACT: The title compound, [Co(CN)(C(3)H(9)P)(4)], was obtained as a product of the reaction of [Co(PMe(3))(4)] with a molar equivalent of 2,6-difluoro-benzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal-bipyramidal coordination enviroment in which the cyano group and one of the PMe(3) groups are in the axial positions.

SUBMITTER: Xu X

PROVIDER: S-EPMC3099961 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Cyanidotetra-kis-(trimethyl-phosphine)cobalt(I).

Xu Xiaofeng X Feng Lei L Li Xiaoyan X

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The title compound, [Co(CN)(C(3)H(9)P)(4)], was obtained as a product of the reaction of [Co(PMe(3))(4)] with a molar equivalent of 2,6-difluoro-benzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal-bipyramidal coordination enviroment in which the cyano group and one of the PMe(3) groups are in the axial positions. ...[more]

PMID: 21754010

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