Unknown

Dataset Information

0

Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O)copper(II) N,N-dimethyl-formamide disolvate.


ABSTRACT: In the title complex, [Cu(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Cu(II) ion, lying on an inversion center, is six-coordinated in a slightly distorted octa-hedral geometry. Two N atoms and two O atoms from two H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb-oxy-lic acid) ligands are in the equatorial plane. The axial positions are occupied by two O atoms from two water mol-ecules. A two-dimensional supra-molecular network parallel to (001) is constructed by N-H?O and O-H?O hydrogen bonds. An intra-molecular O-H?O hydrogen bond is also observed.

SUBMITTER: He LZ 

PROVIDER: S-EPMC3007369 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

altmetric image

Publications

Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-κN,O)copper(II) N,N-dimethyl-formamide disolvate.

He Lan-Zhen LZ   Li Shi-Jie SJ   Song Wen-Dong WD   Miao Dong-Liang DL  

Acta crystallographica. Section E, Structure reports online 20100707 Pt 8


In the title complex, [Cu(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Cu(II) ion, lying on an inversion center, is six-coordinated in a slightly distorted octa-hedral geometry. Two N atoms and two O atoms from two H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb-oxy-lic acid) ligands are in the equatorial plane. The axial positions are occupied by two O atoms from two water mol-ecules. A two-dimensional supra-molecular network parallel to (001) is constructed by N-H⋯O and O-H⋯O hydrogen bonds  ...[more]

Similar Datasets

| S-EPMC3238758 | biostudies-literature
| S-EPMC2980198 | biostudies-literature
| S-EPMC3009030 | biostudies-literature
| S-EPMC2983735 | biostudies-literature
| S-EPMC3006990 | biostudies-literature
| S-EPMC2977566 | biostudies-literature
| S-EPMC3089267 | biostudies-literature
| S-EPMC3151971 | biostudies-literature
| S-EPMC3050148 | biostudies-literature
| S-EPMC3007488 | biostudies-literature