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Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-?P}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-?C,N]palladium(II) dichloro-methane solvate.

ABSTRACT: In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222?(4)?Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47?(2)°. In the crystal structure, the dimeric unit is generated through the C-H?? contact via a crystallographic inversion centre, while the C-H?Cl contacts in the dimeric centre link the dichlormethane mol-ecules with the Pd complex mol-ecules.

SUBMITTER: Hao XQ 

PROVIDER: S-EPMC2977585 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-κC,N]palladium(II) dichloro-methane solvate.

Hao Xin-Qi XQ   Li Hong-Mei HM   Jiang Hui H   Ma Yong-Tao YT   Song Mao-Ping MP  

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C-H⋯π contact via a crystallographi  ...[more]

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