Unknown

Dataset Information

0

Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-?P}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-?C,N]palladium(II) dichloro-methane solvate.

ABSTRACT: In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222?(4)?Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47?(2)°. In the crystal structure, the dimeric unit is generated through the C-H?? contact via a crystallographic inversion centre, while the C-H?Cl contacts in the dimeric centre link the dichlormethane mol-ecules with the Pd complex mol-ecules.

SUBMITTER: Hao XQ 

PROVIDER: S-EPMC2977585 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-κC,N]palladium(II) dichloro-methane solvate.

Hao Xin-Qi XQ   Li Hong-Mei HM   Jiang Hui H   Ma Yong-Tao YT   Song Mao-Ping MP  

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C-H⋯π contact via a crystallographi  ...[more]

Similar Datasets

Unknown Di-?-bromido-bis-({2-[(4,6-dimethyl-pyrimidin-2-yl)disulfan-yl]-4,6-dimethyl-pyrimidine-?(2)N(1),S(2)}copper(I)).
| S-EPMC3344368 | biostudies-literature
Unknown Bis[2-((4,6-dimethyl-pyrimidin-2-yl){2-[(4,6-dimethyl-pyrimidin-2-yl)sulfan-yl]eth-yl}amino)-eth-yl] disulfide.
| S-EPMC2983405 | biostudies-literature
Unknown Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-?P]palladium(II).
| S-EPMC2959319 | biostudies-literature
Unknown Dicyclo-hex-yl[4-(dimethyl-amino)-phen-yl]phosphine selenide.
| S-EPMC3254574 | biostudies-literature
Unknown 1-(4,6-Dimethyl-pyrimidin-2-yl)thio-urea.
| S-EPMC3238992 | biostudies-literature
Unknown N-Cyclo-hexyl-N-{[3-(4,6-dimeth-oxy-pyrimidin-2-yl-oxy)pyridin-2-yl]meth-yl}4,6-dimeth-oxy-pyrimidin-2-amine.
| S-EPMC3344196 | biostudies-literature
Unknown Di-?-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-?P](pyridine-?N)silver(I)}.
| S-EPMC2969050 | biostudies-literature
Unknown Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.
| S-EPMC2979226 | biostudies-literature
Unknown N-(4,6-Dimethyl-pyrimidin-2-yl)-1H-benzimidazol-2-amine.
| S-EPMC3052168 | biostudies-literature
Unknown Bis(4,6-diamino-pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate.
| S-EPMC2960530 | biostudies-literature