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Di-?-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-?P](pyridine-?N)silver(I)}.

ABSTRACT: The title compound, [Ag(2)I(2)(C(5)H(5)N)(2)(C(18)H(27)P)(2)], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008?(6)?Å. The Ag-P distance is 2.4436?(8)?Å, Ag-N is 2.386?(3)Å and the Ag-I distances are 2.8186?(4) and 2.9449?(5)?Å.

SUBMITTER: Omondi B

PROVIDER: S-EPMC2969050 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-κP](pyridine-κN)silver(I)}.

Omondi Bernard B Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20090331 Pt 4

The title compound, [Ag(2)I(2)(C(5)H(5)N)(2)(C(18)H(27)P)(2)], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag-P distance is 2.4436 (8) Å, Ag-N is 2.386 (3)Å and the Ag-I distances are 2.8186 (4) and 2.9449 (5) Å. ...[more]

PMID: 21582395

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