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{?-[2-(Dimethyl-amino)phen-yl](2-fluoro-phen-yl)methano-lato}penta-methyl-dialuminum(III).

ABSTRACT: Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra-hedral geometry. The dimethyl-aluminium centre is bound by the N and the O atoms of the (2-dimethyl-amino-phen-yl)(2-fluoro-phen-yl)methano-late ligand. The second Al atom is bound by the methano-late O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4?(2):0.6?(2) domain ratio.

SUBMITTER: Gao A

PROVIDER: S-EPMC2977619 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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{μ-[2-(Dimethyl-amino)phen-yl](2-fluoro-phen-yl)methano-lato}penta-methyl-dialuminum(III).

Gao Aihong A Su Qing Q Mu Ying Y

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra-hedral geometry. The dimethyl-aluminium centre is bound by the N and the O atoms of the (2-dimethyl-amino-phen-yl)(2-fluoro-phen-yl)methano-late ligand. The second Al atom is bound by the methano-late O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio. ...[more]

PMID: 21583805

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