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6-Benzyl-2-methyl-1,3-bis-(penta-fluoro-phen-yl)-1,3,6,2-triaza-alumocane.

ABSTRACT: In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra-hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra-molecular Al?F contact [2.5717?(11)?Å], leading to an overall distorted trigonal-bipyramidal coordination environment around Al(III).

SUBMITTER: Kireenko MM

PROVIDER: S-EPMC3515133 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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6-Benzyl-2-methyl-1,3-bis-(penta-fluoro-phen-yl)-1,3,6,2-triaza-alumocane.

Kireenko Marina M MM Zaitsev Kirill V KV Churakov Andrei V AV Zaitseva Galina S GS Karlov Sergey S SS

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra-hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra-molecular Al⋯F contact [2.5717 (11) Å], leading to an overall distorted trigonal-bipyramidal coordination environment around Al(III). ...[more]

PMID: 23284360

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