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Fac-Aqua-(2-carboxy-ethyl-?C,O)trichlorido-tin(IV)-1,4,7,10,13-penta-oxacyclo-penta-deca-ne-water (1/1/2).

ABSTRACT: In the title compound, [Sn(C(3)H(5)O(2))Cl(3)(H(2)O)]·C(10)H(20)O(5)·2H(2)O, the Sn(IV) atom is octa-hedrally coordinated within a fac-CO(2)Cl(3) donor set, arising from the C,O-bidentate carboxy-ethyl ligand, a water mol-ecule and three chloride ligands. In the crystal, supra-molecular chains linked by O-H?O hydrogen bonds propagate along the c axis These chains are connected into layers in the ac plane via C-H?O inter-actions.

SUBMITTER: Tiekink ER

PROVIDER: S-EPMC2979106 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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fac-Aqua-(2-carboxy-ethyl-κC,O)trichlorido-tin(IV)-1,4,7,10,13-penta-oxacyclo-penta-deca-ne-water (1/1/2).

Tiekink Edward R T ER Wardell James L JL Wardell Solange M S V SM

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

In the title compound, [Sn(C(3)H(5)O(2))Cl(3)(H(2)O)]·C(10)H(20)O(5)·2H(2)O, the Sn(IV) atom is octa-hedrally coordinated within a fac-CO(2)Cl(3) donor set, arising from the C,O-bidentate carboxy-ethyl ligand, a water mol-ecule and three chloride ligands. In the crystal, supra-molecular chains linked by O-H⋯O hydrogen bonds propagate along the c axis These chains are connected into layers in the ac plane via C-H⋯O inter-actions. ...[more]

PMID: 21578998

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