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Fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octa-hedrally coordinated within a CCl(3)NO donor set provided by a chelating amido-ethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn-Cl bond distances are correlated with the relative trans influence exerted by the C and carbonyl-O atoms. The three-dimensional crystal packing is stabilized by N-H?O and N-H?Cl hydrogen bonds.

SUBMITTER: Howie RA

PROVIDER: S-EPMC3201406 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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fac-(2-Amido-ethyl-κC,O)trichlorido(urea-κO)tin(IV).

Howie R Alan RA de Lima Geraldo M GM Tiekink Edward R T ER Wardell James L JL Wardell Solange M S V SM

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octa-hedrally coordinated within a CCl(3)NO donor set provided by a chelating amido-ethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn-Cl bond distances are correlated with the relative trans influence exerted by the C and carbonyl-O atoms. The three-dimensional crystal packing is stabilized by N-H⋯O and N-H⋯Cl hydrogen bonds. ...[more]

PMID: 22064619

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