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3-Acetyl-6-chloro-2-methyl-4-phenyl-quinolinium perchlorate.

ABSTRACT: In the title mol-ecular salt, C(18)H(15)ClNO(+)·ClO(4) (-), the quinolin-ium ring system is approximately planar, with a maximum deviation of 0.027?(1)?Å. The dihedral angle formed between the mean planes of the quinolinium ring system and the benzene ring is 78.46?(3)°. In the crystal structure, inter-molecular N-H?O and C-H?O hydrogen bonds link the cations and anions into a three-dimensional network. The crystal structure is further consolidated by C-H?? inter-actions.

SUBMITTER: Shahani T

PROVIDER: S-EPMC2979191 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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3-Acetyl-6-chloro-2-methyl-4-phenyl-quinolinium perchlorate.

Shahani Tara T Fun Hoong-Kun HK Sarveswari S S Vijayakumar V V Reddy B Palakshi BP

Acta crystallographica. Section E, Structure reports online 20100428 Pt 5

In the title mol-ecular salt, C(18)H(15)ClNO(+)·ClO(4) (-), the quinolin-ium ring system is approximately planar, with a maximum deviation of 0.027 (1) Å. The dihedral angle formed between the mean planes of the quinolinium ring system and the benzene ring is 78.46 (3)°. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. The crystal structure is further consolidated by C-H⋯π inter-actions. ...[more]

PMID: 21579229

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