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(Dimethyl-formamide-?O)[2-meth-oxy-6-(2-pyridylmethyl-imino-meth-yl)phenolato-?N,N',O](thio-cyanato-?N)copper(II).

ABSTRACT: In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N',O-tridentate 2-meth-oxy-6-(2-pyridylmethyl-imino-meth-yl)phenolate ligand, an N-bonded thio-cyanate ion and an O-bonded dimethyl-formamide (DMF) mol-ecule, resulting in a distorted CuN(3)O(2) square-based pyramidal geometry for the metal ion, with the DMF O atom in the apical site. The dihedral angle between the aromatic rings in the ligand is 8.70?(16)°. The S atom is disordered over two positions in a 0.901?(6):0.099?(6) ratio. In the crystal, mol-ecules inter-act by way of ?-? stacking inter-actions [centroid-centroid separation = 3.720?(2)?Å].

SUBMITTER: Bao Q

PROVIDER: S-EPMC2979238 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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(Dimethyl-formamide-κO)[2-meth-oxy-6-(2-pyridylmethyl-imino-meth-yl)phenolato-κN,N',O](thio-cyanato-κN)copper(II).

Bao Qianqian Q Chen Xiaodan X Rong Rong R Shi Feifei F

Acta crystallographica. Section E, Structure reports online 20100424 Pt 5

In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N',O-tridentate 2-meth-oxy-6-(2-pyridylmethyl-imino-meth-yl)phenolate ligand, an N-bonded thio-cyanate ion and an O-bonded dimethyl-formamide (DMF) mol-ecule, resulting in a distorted CuN(3)O(2) square-based pyramidal geometry for the metal ion, with the DMF O atom in the apical site. The dihedral angle between the aromatic rings in the ligand is 8.70 (16)°. The S atom is disordered over two p ...[more]

PMID: 21579045

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