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Bis(propane-1,3-diaminium) hexa-fluoridoferrate(III) fluoride trihydrate.

ABSTRACT: The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin-ium [(H(2)dap)(2+)] cations, an octa-hedral [FeF(6)](3-) anion, an isolated F(-) anion and three water mol-ecules of solvation. Each [FeF(6)](3-) anion is surrounded by four separate hydrogen-bonded water mol-ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N-H?F hydrogen bonds, resulting in a three-dimensional structure.

SUBMITTER: Zouaghi A

PROVIDER: S-EPMC2979354 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Bis(propane-1,3-diaminium) hexa-fluoridoferrate(III) fluoride trihydrate.

Zouaghi Aymen A Benali Amor A Maisonneuve Vincent V Leblanc Marc M

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin-ium [(H(2)dap)(2+)] cations, an octa-hedral [FeF(6)](3-) anion, an isolated F(-) anion and three water mol-ecules of solvation. Each [FeF(6)](3-) anion is surrounded by four separate hydrogen-bonded water mol-ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N-H⋯F hydrogen bonds, resulting in a three-dimen ...[more]

PMID: 21579337

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