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Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

ABSTRACT: In the title compound, [Cu(C??H??P?)?][GaCl?], the Cu(I) atom in the complex cation is P,P'-chelated by two 1,3-bis-(diphenyl-phosphan-yl)propane ligands in a distorted tetra-hedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetra-hedral geometry. In the crystal, weak C-H?? inter-actions occur between adjacent complex cations.

SUBMITTER: Wang NN

PROVIDER: S-EPMC3393151 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

Wang Nian-Nian NN Hu Feng F Duan Tai-Ke TK Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20120602 Pt 7

In the title compound, [Cu(C₂₇H₂₆P₂)₂][GaCl₄], the Cu(I) atom in the complex cation is P,P'-chelated by two 1,3-bis-(diphenyl-phosphan-yl)propane ligands in a distorted tetra-hedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetra-hedral geometry. In the crystal, weak C-H⋯π inter-actions occur between adjacent complex cations. ...[more]

PMID: 22807719

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