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Redetermination of diammonium thio-molybdate.

ABSTRACT: In contrast to the previous structure determinations of the title structure, (NH(4))(2)[MoS(4)], the present determination at 173?K localized the positions of the H atoms. The title structure belongs to the ?-K(2)SO(4) family and all the ions are located on crystallographic mirror planes. The ions are held together by N-H?S hydrogen bonds (some of which are bifurcated), forming a three-dimensional network. One of the N atoms has nine contacts to the S atoms shorter than 4?Å, and the other has ten.

SUBMITTER: Hill B

PROVIDER: S-EPMC2979694 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Redetermination of diammonium thio-molybdate.

Hill Björn B Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

In contrast to the previous structure determinations of the title structure, (NH(4))(2)[MoS(4)], the present determination at 173 K localized the positions of the H atoms. The title structure belongs to the β-K(2)SO(4) family and all the ions are located on crystallographic mirror planes. The ions are held together by N-H⋯S hydrogen bonds (some of which are bifurcated), forming a three-dimensional network. One of the N atoms has nine contacts to the S atoms shorter than 4 Å, and the other has te ...[more]

PMID: 21579587

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