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4-(Methyl-sulfon-yl)piperazin-1-ium chloride.

ABSTRACT: In the title mol-ecular salt, C(5)H(13)N(2)O(2)S(+)·Cl(-), the complete cation is generated by crystallographic mirror symmetry, with both N atoms, the S atom and one C atom lying on the reflecting plane. The chloride ion also lies on the mirror plane. The piperazinium ring adopts a chair conformation and the N-S bond adopts an equatorial orientation. In the crystal structure, the component ions are linked into a three-dimensional framework by inter-molecular N-H?Cl and C-H?Cl hydrogen bonds.

SUBMITTER: Fun HK

PROVIDER: S-EPMC2979749 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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4-(Methyl-sulfon-yl)piperazin-1-ium chloride.

Fun Hoong-Kun HK Yeap Chin Sing CS Chidan Kumar C S CS Yathirajan H S HS Narayana B B

Acta crystallographica. Section E, Structure reports online 20100116 Pt 2

In the title mol-ecular salt, C(5)H(13)N(2)O(2)S(+)·Cl(-), the complete cation is generated by crystallographic mirror symmetry, with both N atoms, the S atom and one C atom lying on the reflecting plane. The chloride ion also lies on the mirror plane. The piperazinium ring adopts a chair conformation and the N-S bond adopts an equatorial orientation. In the crystal structure, the component ions are linked into a three-dimensional framework by inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21579786

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