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(2R)-4-[(9H-Fluoren-9-ylmeth-oxy)carbon-yl]-2-methyl-piperazin-1-ium chloride.

ABSTRACT: The synthesis of the title salt, C(20)H(23)N(2)O(2) (+)·Cl(-), was carried out with a precursor of known absolute configuration (R) and the X-ray analysis confirmed that the product retained the absolute configuration. In the crystal, the dominant packing motif is a chain running along [010] generated by N-H?Cl hydrogen bonding. C-H?O and C-H?Cl inter-actions are also observed.

SUBMITTER: Ertan A

PROVIDER: S-EPMC3239028 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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(2R)-4-[(9H-Fluoren-9-ylmeth-oxy)carbon-yl]-2-methyl-piperazin-1-ium chloride.

Ertan Anne A Sharma Parhalad P Nagaraju Dokka D Deepthi K K Manjunatha Sulur G SG

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

The synthesis of the title salt, C(20)H(23)N(2)O(2) (+)·Cl(-), was carried out with a precursor of known absolute configuration (R) and the X-ray analysis confirmed that the product retained the absolute configuration. In the crystal, the dominant packing motif is a chain running along [010] generated by N-H⋯Cl hydrogen bonding. C-H⋯O and C-H⋯Cl inter-actions are also observed. ...[more]

PMID: 22199876

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