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[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dimethyl-tin(IV).

ABSTRACT: The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27?(9)°. The presence of an intra-molecular O-H?N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.

SUBMITTER: Lee SM

PROVIDER: S-EPMC2979755 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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[N'-(5-Bromo-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]dimethyl-tin(IV).

Lee See Mun SM Mohd Ali Hapipah H Lo Kong Mun KM

Acta crystallographica. Section E, Structure reports online 20100116 Pt 2

The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure. ...[more]

PMID: 21579636

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