Browse
Submit Data
Databases
API
Help

Dataset Information

13 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[N'-(3-Meth-oxy-2-oxidobenzyl-idene)nicotinohydrazidato]dimethyl-tin(IV).

ABSTRACT: In the title complex, [Sn(CH(3))(2)(C(14)H(11)N(3)O(3))], the Sn atom is in a distorted trigonal-bipyramidal coordination, with Sn-O distances of 2.138?(2) and 2.176?(2)?Å. The dihedral angles between the two chelated benzene rings and the O-Sn-N group are 71.73?(9) and 83.30?(9)°.

SUBMITTER: Gao Z

PROVIDER: S-EPMC2970494 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[N'-(3-Meth-oxy-2-oxidobenzyl-idene)nicotinohydrazidato]dimethyl-tin(IV).

Gao Zhongjun Z Chen Wandong W Wang Yanbao Y Zhao Guangwang G

Acta crystallographica. Section E, Structure reports online 20090919 Pt 10

In the title complex, [Sn(CH(3))(2)(C(14)H(11)N(3)O(3))], the Sn atom is in a distorted trigonal-bipyramidal coordination, with Sn-O distances of 2.138 (2) and 2.176 (2) Å. The dihedral angles between the two chelated benzene rings and the O-Sn-N group are 71.73 (9) and 83.30 (9)°. ...[more]

PMID: 21577754

Similar Datasets

[N'-(3-Meth-oxy-2-oxidobenzyl-idene)nicotinohydrazidato]diphenyl-tin(IV).

Project description:The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(14)H(11)N(3)O(3))], contains two crystallographically independent mol-ecules that differ predominantly in the torsion of the phenyl rings. In both mol-ecules, the Sn(IV) ion is in a distored trigonal-bipyramidal geometry. The Sn-O distances are in the range 2.055 (2)-2.143 (2) Å.

| S-EPMC2969951 | biostudies-literature

[4-Chloro-N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Project description:In the title mol-ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37?(2)°. The Sn atom is coordinated by one N [Sn-N = 2.187?(3)?Å], two O [Sn-O = 2.123?(3) and 2.174?(3)?Å] and two C [Sn-C = 2.096?(4) and 2.101?(4)?Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter-molecular C-H?O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers with an Sn?Sn separation of 4.330?(6)?Å, and ?-? inter-actions [centroid-centroid distance of 3.690?(5)?Å between the benzene rings of neighbouring mol-ecules].

| S-EPMC2967882 | biostudies-other

(2,2'-Bipyridine-?N,N'){[(3-meth-oxy-2-oxidobenzyl-idene-?O)hydrazono]methano-lato-?N,O}dimethyl-tin(IV).

Project description:In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097?(3)-2.098?(3), 2.298?(2)-2.623?(2) and 2.157?(2)-2.266?(2)?Å, respectively. The mol-ecular structure of the monomeric compound is stabilized by three intra-molecular C-H?O hydrogen bonds, all involving bipyridine C-H groups.

| S-EPMC2961040 | biostudies-literature

[N-(3-Meth-oxy-2-oxidobenzyl-idene-?O)alaninato-?N,O]diphenyl-tin(IV).

Project description:The Sn atom of the title compound, [Sn(C(6)H(5))(2)(C(11)H(11)NO(4))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with the O atoms in the axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand.

| S-EPMC2968303 | biostudies-literature

[N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dimethyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordin-ation; the axial O-Sn-O angle is 155.22?(5)°. The tridentate N'-(5-chloro-2-oxidobenzyl-idene)-3-hydr-oxy-2-naphthohydrazidate dianion is stabilized by an intra-molecular O-H?N hydrogen bond.

| S-EPMC2969223 | biostudies-literature

[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dimethyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27?(9)°. The presence of an intra-molecular O-H?N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.

| S-EPMC2979755 | biostudies-literature

[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H?N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5?(1)°. In the crystal, weak inter-molecular C-H?O hydrogen bonds and ?-? inter-actions between the aromatic rings [centroid-centroid distance = 3.816?(3)?Å] link the mol-ecules into centrosymmetric dimers.

| S-EPMC3212120 | biostudies-literature

Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-?O,N,O']tin(IV).

Project description:In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, inter-molecular C-H?O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

| S-EPMC2961818 | biostudies-other

[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dibutyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60?(1):0.40?(1) ratio.

| S-EPMC2977471 | biostudies-literature

[N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]diphenyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7?(2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2?(3)°. Intra-molecular O-H?N hydrogen bonding is present in the crystal structure.

| S-EPMC2971880 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data