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(2,2'-Bipyridine-?N,N'){[(3-meth-oxy-2-oxidobenzyl-idene-?O)hydrazono]methano-lato-?N,O}dimethyl-tin(IV).

ABSTRACT: In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097?(3)-2.098?(3), 2.298?(2)-2.623?(2) and 2.157?(2)-2.266?(2)?Å, respectively. The mol-ecular structure of the monomeric compound is stabilized by three intra-molecular C-H?O hydrogen bonds, all involving bipyridine C-H groups.

SUBMITTER: Shuja S

PROVIDER: S-EPMC2961040 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridine-κN,N'){[(3-meth-oxy-2-oxidobenzyl-idene-κO)hydrazono]methano-lato-κN,O}dimethyl-tin(IV).

Shuja Shaukat S Ali Saqib S Tahir M Nawaz MN Khalid Nasir N Khan Islam Ullah IU

Acta crystallographica. Section E, Structure reports online 20080307 Pt 4

In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097 (3)-2.098 (3), 2.298 (2)-2.623 (2) and 2.157 (2)-2.266 (2) Å, respectively. The mol-ecular structure of the monomeric compound is stabilized by three intra-molecular C-H⋯O hydrogen bonds, all involving bipyridine C-H groups. ...[more]

PMID: 21201994

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