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Dichlorido[N,N-diethyl-N'-(2-pyridyl-methyl-ene)ethane-1,2-diamine]mercury(II).

ABSTRACT: The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N'-(2-pyridylmethyl-ene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes is 88.6?(1)°. The Hg-N distances including the pyridine N and the ammonium N atom are about 0.20?Å longer than the Hg-N distance including the imino N atom.

SUBMITTER: Kim YI 

PROVIDER: S-EPMC2979770 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Dichlorido[N,N-diethyl-N'-(2-pyridyl-methyl-ene)ethane-1,2-diamine]mercury(II).

Kim Young-Inn YI   Seo Hoe-Joo HJ   Kim Ji-Hoon JH   Lee You-Soon YS   Kang Sung Kwon SK  

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2

The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N'-(2-pyridylmethyl-ene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes is 88.6 (1)°. The Hg-N distances including the pyridine N and the ammonium N atom are about 0.20 Å longer than the Hg-N distance including the imino N atom. ...[more]

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