Unknown

Dataset Information

0

?-1,2-Bis(diethyl-phosphino)ethane-?P:P'-bis-{[1,2-bis-(diethyl-phosphino)ethane-?P,P']trichloridonitrosyl-tungsten(II)}.

ABSTRACT: The title binuclear compound, [W(2)Cl(6)(NO)(2)(C(10)H(22)P(2))(3)], contains two W atoms which are bridged by a bis-(diethyl-phosphino)-ethane (depe) ligand. The seven-coord-inated tungsten(II) centres display distorted penta-gonal-bipyramidal geometries with trans nitrosyl and chloride ligands. The title mol-ecule lies on a crystallographic inversion centre. The ethane group of the non-bridging depe ligand is positionally disordered, with site-occupancy factors of 0.63 and 0.37. In the crystal structure, the binuclear mol-ecules are linked by weak inter-molecular C-H?O and C-H?Cl inter-actions. In addition, weak intra-molecular C-H?Cl inter-actions are also present.

SUBMITTER: Avramovic N 

PROVIDER: S-EPMC2960239 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

μ-1,2-Bis(diethyl-phosphino)ethane-κP:P'-bis-{[1,2-bis-(diethyl-phosphino)ethane-κP,P']trichloridonitrosyl-tungsten(II)}.

Avramović Nataša N   Blacque Olivier O   Schmalle Helmut W HW   Berke Heinz H  

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

The title binuclear compound, [W(2)Cl(6)(NO)(2)(C(10)H(22)P(2))(3)], contains two W atoms which are bridged by a bis-(diethyl-phosphino)-ethane (depe) ligand. The seven-coord-inated tungsten(II) centres display distorted penta-gonal-bipyramidal geometries with trans nitrosyl and chloride ligands. The title mol-ecule lies on a crystallographic inversion centre. The ethane group of the non-bridging depe ligand is positionally disordered, with site-occupancy factors of 0.63 and 0.37. In the crystal  ...[more]

Similar Datasets

Unknown catena-Poly[[(nitrato-κO,O')silver(I)]-μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P'].
| S-EPMC2961910 | biostudies-literature
Unknown trans-Bis[1,2-bis-(dimethyl-phosphino)-ethane]-bromido-nitrosyl-tungsten(0).
| S-EPMC2915161 | biostudies-literature
Unknown Bis{1,2-bis-[bis-(3-hydroxy-prop-yl)phosphino]ethane}dichloridoiron(II).
| S-EPMC2979366 | biostudies-literature
Unknown trans-Bis{1,2-bis-[bis-(2-methoxy-ethyl)phosphino]ethane}dichloridoiron(II).
| S-EPMC2983552 | biostudies-literature
Unknown Bis[μ-1,2-bis-(diphenyl-phosphino)methane-κP:P']bis-[(η-ethene)nickel(0)] toluene disolvate.
| S-EPMC2960292 | biostudies-literature
Unknown [1,2-Bis(diisopropyl-phosphino)-1,2-dicarba-closo-dodeca-borane-κP,P']dichloridomercury(II).
| S-EPMC2915082 | biostudies-literature
Unknown 1,2-Bis(diphenyl-phosphino)-1,2-diethyl-hydrazine.
| S-EPMC2979499 | biostudies-literature
Unknown [?-1,2-Bis(diphenyl-phosphino)ethane-?P:P']bis-{[1,2-bis-(diphenyl-phosphino)ethane-?P,P']cyanidocopper(I)} methanol disolvate.
| S-EPMC3007356 | biostudies-literature
Unknown Bis[1,2-bis-(dimethyl-phosphino)ethane-κP,P']rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclo-octa-diene]rhodium(I).
| S-EPMC2959718 | biostudies-literature
Unknown [μ-1,2-Bis(diphenyl-phosphan-yl)-1,2-diethyl-hydrazine-κP:P']bis-[chlorido-gold(I)] tetra-hydro-furan disolvate.
| S-EPMC3051471 | biostudies-literature