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Bis(N-phenyl-ethane-1,2-diamine)dithio-cyanato-nickel(II).

ABSTRACT: The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol-ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl-ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio-cyanate ligands, giving a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (100) by N-H?S inter-actions.

SUBMITTER: Wang CY

PROVIDER: S-EPMC2979796 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Bis(N-phenyl-ethane-1,2-diamine)dithio-cyanato-nickel(II).

Wang Chen-Yi CY Cao Feng F Wang Ping P Lv Chun-Yan CY Wu Xiang X

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2

The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol-ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl-ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio-cyanate ligands, giving a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (100) by N-H⋯S inte ...[more]

PMID: 21579606

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