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Tris(ethane-1,2-diamine-κN,N')nickel(II) diiodide.

ABSTRACT: The title compound, [Ni(C(2)H(8)N(2))(3)]I(2), crystallizes with an [Ni(en)(3) (2+)] cation (en is ethane-1,2-diamine) and two iodide ions in the asymmetric unit. Two of the en ligands surrrounding the Ni(2+) ion have disordered C atoms, while the third exhibits extensive weak N-H⋯I inter-actions with the two iodide ions that extend throughout the crystalline lattice, producing an infinite network along (011).

SUBMITTER: Brewer G

PROVIDER: S-EPMC2979990 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Tris(ethane-1,2-diamine-κN,N')nickel(II) diiodide.

Brewer Greg G Butcher Ray J RJ Jasinski Jerry P JP

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

The title compound, [Ni(C(2)H(8)N(2))(3)]I(2), crystallizes with an [Ni(en)(3) (2+)] cation (en is ethane-1,2-diamine) and two iodide ions in the asymmetric unit. Two of the en ligands surrrounding the Ni(2+) ion have disordered C atoms, while the third exhibits extensive weak N-H⋯I inter-actions with the two iodide ions that extend throughout the crystalline lattice, producing an infinite network along (011). ...[more]

PMID: 21579912

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