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Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) dihydrate.

ABSTRACT: The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa-cyano-molybdate(IV), [Mo(CN)(8)](4-), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti-prismatic shape, while the geometry around the Ni atom is distorted octa-hedral. The complex ions and water mol-ecules are linked by hydrogen bonds.

SUBMITTER: Liu WY

PROVIDER: S-EPMC2960526 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) dihydrate.

Liu Wen-Yan WY Zhou Hu H Guo Ji-Xi JX Yuan Ai-Hua AH

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9

The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa-cyano-molybdate(IV), [Mo(CN)(8)](4-), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti-prismatic shape, while the geometry around the Ni atom is distorted octa-hedral. The complex ions and water mol-ecules are linked by hydrogen bonds. ...[more]

PMID: 21201605

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