Browse
Submit Data
Databases
API
Help

Dataset Information

39 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2,4-Dichloro-phen-yl)(diphenyl-phosphor-yl)methanol.

ABSTRACT: In the title compound, C(19)H(15)Cl(2)O(2)P, the dihedral angle between the mean planes of the phenyl rings bonded to the P atom is 75.4 (1)°. In the crystal, mol-ecules are linked into chains running along the a axis by inter-molecular O-H⋯O hydrogen bonds. Mol-ecules are further connected into a three-dimensional array by weak C-H⋯O inter-actions.

SUBMITTER: Liu WY

PROVIDER: S-EPMC2979971 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

(Diphenyl-phosphor-yl)(2-nitro-phen-yl)methanol.

Project description:In the title compound, C(19)H(16)NO(4)P, the dihedral angle between the mean planes of the phenyl rings bonded to the P atom is 75.4 (1)°. In the crystal, mol-ecules are linked into chains running along the a axis by inter-molecular O-H⋯O hydrogen bonds. Mol-ecules are further connected into a three-dimensional array by weak C-H⋯O hydrogen bonds.

| S-EPMC3008110 | biostudies-literature

(2-Chloro-phen-yl)(diphenyl-phosphor-yl)methanol.

Project description:The title compound, C(19)H(16)ClO(2)P, was obtained by the reaction of diphenyl-phosphine oxide with 2-chloro-benzaldehyde. The mol-ecule has a tetra-hedral structure at the P atom. The dihedral angle between the phenyl rings attached to the P atom is 80.4 (1)°. The mol-ecules are linked together by inter-molecular O-H⋯O and C-H⋯O hydrogen-bonding inter-actrions. The crystal studied was an inversion twin.

| S-EPMC2915293 | biostudies-literature

(Dimeth-oxy-phosphor-yl)(furan-2-yl)methyl 2-(2,4-dichloro-phen-oxy)acetate.

Project description:In the title compound, C(15)H(15)Cl(2)O(7)P, the benzene and furan rings form a dihedral angle of 73.54?(1)°. In the crystal, weak inter-molecular C-H?O hydrogen bonds link the mol-ecules into layers parallel to (100).

| S-EPMC3009241 | biostudies-literature

N-(2,4-Dichloro-phen-yl)benzamide.

Project description:The conformations of the N-H and C=O bonds in the structure of the title compound, C(13)H(9)Cl(2)NO, are anti to each other, similar to that observed in N-phenyl-benzamide, N-(2-chloro-phen-yl)benzamide, N-(4-chloro-phen-yl)benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and other benzanilides. The amide -NHCO- group forms a dihedral angle of 33.0 (2)° with the benzoyl ring, while the rings are almost coplanar, making a dihedral angle of 2.6 (2)°). The mol-ecules are linked by N-H⋯O hydrogen bonds into infinite chains running along the b axis.

| S-EPMC2961566 | biostudies-literature

2,4-Dichloro-N-(3,4-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-H bond is syn to the meta-chloro residue in the aniline benzene ring. The two aromatic rings are tilted relative to each other by 68.9?(1)°. N-H?O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.

| S-EPMC2977279 | biostudies-literature

2,4-Dichloro-N-(2,3-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atoms in the aniline and sulfonyl benzene rings. The C-SO(2)-NH-C torsion angle is -51.98 (18)°. The sulfonyl and aniline benzene rings are tilted by 67.7 (1)° relative to each other. An intra-molecular N-H⋯Cl hydrogen bond occurs.

| S-EPMC3247310 | biostudies-literature

2,4-Dichloro-N-(3,5-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(7)Cl(4)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atom of the sulfonyl-benzene ring and one of the meta-Cl atoms of the aniline ring. The C-SO(2)-NH-C torsion angle is -93.9 (2)°. The benzene rings are tilted relative to each other by 61.9 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

| S-EPMC3247380 | biostudies-literature

2-Amino-6-(2,4-dichloro-phen-yl)-4-oxo-3,5-diphenyl-cyclo-hex-2-enecarbonitrile.

Project description:In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo-hexene ring has a sofa conformation. All the substituents in the cyclo-hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N-H⋯O hydrogen bonds, forming a chain extending along the b axis and through C-H⋯N and C-H⋯Cl inter-actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding.

| S-EPMC2983276 | biostudies-literature

N-(2,4-Dichloro-phen-yl)-2,4-dimethyl-benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the mol-ecule is bent at the S atom with an C-SO(2)-NH-C torsion angle of -69.9?(2)°. The dihedral angle between the sulfonyl and aniline benzene rings is 44.0?(1)°. The crystal structure features inversion dimers linked by pairs of N-H?O hydrogen bonds. An intra-molecular N-H?Cl hydrogen bond is also observed.

| S-EPMC3011417 | biostudies-literature

2,4-Dichloro-N-(2,4-dimethyl-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the C-SO(2)-NH-C torsion angle is -71.4 (4)°. The sulfonyl and aniline benzene rings are tilted relative to one another by 44.6 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

| S-EPMC3247564 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data