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2-Amino-6-(2,4-dichloro-phen-yl)-4-oxo-3,5-diphenyl-cyclo-hex-2-enecarbonitrile.

ABSTRACT: In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo-hexene ring has a sofa conformation. All the substituents in the cyclo-hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N-H?O hydrogen bonds, forming a chain extending along the b axis and through C-H?N and C-H?Cl inter-actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding.

SUBMITTER: Ali AJ

PROVIDER: S-EPMC2983276 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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2-Amino-6-(2,4-dichloro-phen-yl)-4-oxo-3,5-diphenyl-cyclo-hex-2-enecarbonitrile.

Ali A Jahubar AJ Athimoolam S S Bahadur S Asath SA Raja V P Alex VP

Acta crystallographica. Section E, Structure reports online 20100918 Pt 10

In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo-hexene ring has a sofa conformation. All the substituents in the cyclo-hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N-H⋯O hydrogen bonds, forming a chain extending along the b axis and through C-H⋯N and C-H⋯Cl inter-actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding. ...[more]

PMID: 21587572

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