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Poly[(?(6)-benzene-1,3,5-tricarboxyl-ato-?O:O:O:O:O:O)tris-(N,N-dimethyl-formamide-?O)tris-(?(3)-formato-?O:O')trimagnesium(II)].

ABSTRACT: The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhib-its a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxyl-ate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethyl-formamide mol-ecule, two O atoms from two ?(6)-benzene-1,3,5-tricarboxyl-ate ligands and three O atoms from three ?(3)-formate ligands in a distorted octa-hedral geometry.

SUBMITTER: Yeh CT

PROVIDER: S-EPMC2983117 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Poly[(μ(6)-benzene-1,3,5-tricarboxyl-ato-κO:O:O:O:O:O)tris-(N,N-dimethyl-formamide-κO)tris-(μ(3)-formato-κO:O')trimagnesium(II)].

Yeh Chun-Ting CT Liu Hsin-Kuan HK Lin Chia-Jing CJ Lin Chia-Her CH

Acta crystallographica. Section E, Structure reports online 20100925 Pt 10

The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhib-its a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxyl-ate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethyl-formamide mol-ecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxyl-ate ligands and three O atoms from three μ(3)-formate ligands in a distorted octa-hedral geometry. ...[more]

PMID: 21587431

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