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Poly[(?(4)-benzene-1,3,5-tricarboxyl-ato)bis-(N,N-dimethyl-formamide)-cerium(III)].

ABSTRACT: The asymmetric unit of the title rare earth coordination polymer, [Ce(C(9)H(3)O(6))(C(3)H(7)NO)(2)](n), contains one eight-coordinated Ce(3+) ion, one benzene-1,3,5-tricarboxyl-ate (BTC) ligand and two coordinated N,N-dimethyl-formamide (DMF) mol-ecules. The Ce(3+) ion is coordinated by six O atoms from four carboxyl-ate groups of the BTC ligands and by two O atoms from two terminal DMF mol-ecules.

SUBMITTER: Li Z

PROVIDER: S-EPMC3212115 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Poly[(μ(4)-benzene-1,3,5-tricarboxyl-ato)bis-(N,N-dimethyl-formamide)-cerium(III)].

Li Zhongyue Z Liu Kun K

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

The asymmetric unit of the title rare earth coordination polymer, [Ce(C(9)H(3)O(6))(C(3)H(7)NO)(2)](n), contains one eight-coordinated Ce(3+) ion, one benzene-1,3,5-tricarboxyl-ate (BTC) ligand and two coordinated N,N-dimethyl-formamide (DMF) mol-ecules. The Ce(3+) ion is coordinated by six O atoms from four carboxyl-ate groups of the BTC ligands and by two O atoms from two terminal DMF mol-ecules. ...[more]

PMID: 22090817

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