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Aqua-(trifluoro-methane-sulfonato)-bis-(1,3,7-trimethyl-purine-2,6-dione)silver(I).

ABSTRACT: In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol-ecule and the trifluoro-methane-sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol-ecules are roughly coplanar [dihedral angle = 5.81?(5)°]. In the crystal, mol-ecules self-assemble into a linear supra-molecular chain along the c axis via O-H?O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C-H?O inter-actions.

SUBMITTER: Arman HD

PROVIDER: S-EPMC2983140 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Aqua-(trifluoro-methane-sulfonato)-bis-(1,3,7-trimethyl-purine-2,6-dione)silver(I).

Arman Hadi D HD Miller Tyler T Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10

In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol-ecule and the trifluoro-methane-sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol-ecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, mol-ecules self-assemble into a linear supra-molecular chain along the c axis via O-H⋯O hydrogen bonds involving the coordinate ...[more]

PMID: 21587369

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