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Catena-Poly[hexaaqua-1?O,2?O,3?O-(?(4)-3,5-dicarboxylatopyrazol-1-ido-3':1:2:3?O:N,O:N,O:O)(?(2)-3,5-dicarboxylatopyrazol-1-ido-1:2?N,O:N,O)-1,2-dicopper(II)-3-manganese(II)].

ABSTRACT: In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa-hedral geometry. Two pyrazolyl-3,5-dicarboxyl-ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn(II )ions into chains extending along [100]. Both independent coordinated water mol-ecules on the Mn(II) ion are disordered in a 50:50 fashion.

SUBMITTER: Zhou XH

PROVIDER: S-EPMC2983142 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[hexaaqua-1κO,2κO,3κO-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3':1:2:3κO:N,O:N,O:O)(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κN,O:N,O)-1,2-dicopper(II)-3-manganese(II)].

Zhou Xin-Hui XH

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa-hedral geometry. Two pyrazolyl-3,5-dicarboxyl-ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn(II )ions into chains extending along [100]. Both independent coordinated water mol-ec ...[more]

PMID: 21587446

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