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Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).


ABSTRACT: In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, ?-? inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances = 3.8821?(9) and 3.9502?(10)?Å, respectively] stabilize the structure.

SUBMITTER: Akbarzadeh Torbati N 

PROVIDER: S-EPMC2983147 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II).

Akbarzadeh Torbati Niloufar N   Rezvani Ali Reza AR   Safari Nasser N   Amani Vahid V   Khavasi Hamid Reza HR  

Acta crystallographica. Section E, Structure reports online 20100911 Pt 10


In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π-π inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances  ...[more]

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