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Dibromido(2,9-dimethyl-1,10-phenanthroline-?N,N')mercury(II).

ABSTRACT: In the mol-ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter-molecular C-H?Br hydrogen bonds link the mol-ecules into chains along the b axis. There are ?-? contacts between the phenanthroline rings [centroid-centroid distances = 3.806?(4), 3.819?(4), 3.739?(3), 3.690?(3), 3.619?(4) and 3.674?(3)?Å].

SUBMITTER: Alizadeh R

PROVIDER: S-EPMC2977550 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Dibromido(2,9-dimethyl-1,10-phenanthroline-κN,N')mercury(II).

Alizadeh Robabeh R Heidari Amene A Ahmadi Roya R Amani Vahid V

Acta crystallographica. Section E, Structure reports online 20090402 Pt 5

In the mol-ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter-molecular C-H⋯Br hydrogen bonds link the mol-ecules into chains along the b axis. There are π-π contacts between the phenanthroline rings [centroid-centroid distances = 3.806 (4), 3.819 (4), 3.739 (3), 3.690 (3), 3.619 (4) and 3.674 (3 ...[more]

PMID: 21583736

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