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Catena-Poly[[[diaqua-cadmium(II)]-bis-[?-3,5-bis-(isonicotinamido)benzoato]] tetra-hydrate].

ABSTRACT: The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis-(iso-nicotin-amido)-benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ?). J. Coord. Chem.62, 2421-2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octa-hedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N-H?O, O-H?O and O-H?N hydrogen bonds as well as ?-? inter-actions [centroid-centroid distance of 3.639?(2)?Å], giving a three-dimensional supra-molecular framework.

SUBMITTER: Chen MS 

PROVIDER: S-EPMC2983169 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[[diaqua-cadmium(II)]-bis-[μ-3,5-bis-(isonicotinamido)benzoato]] tetra-hydrate].

Chen Man-Sheng MS   Deng Yi-Fang YF   Zhang Chun-Hua CH   Kuang Dai-Zhi DZ  

Acta crystallographica. Section E, Structure reports online 20100911 Pt 10

The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis-(iso-nicotin-amido)-benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). J. Coord. Chem.62, 2421-2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octa-hedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds as well as π-π inter-actions [centro  ...[more]

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