Acetato-(N-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene]-2-{2-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene-amino]-pheneth-yl}aniline)nickel(II) perchlorate.

ABSTRACT: In the title complex, [Ni(CH(3)COO)(C(28)H(26)N(4))]ClO(4), the Ni(II) atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene]-2-(2-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene-amino]-pheneth-yl)aniline donor ligand and two O atoms of the acetate ion in a distorted octa-hedral coordination. The average Ni-N and Ni-O bond lengths are 2.131?(13) and 2.098?(11)?Å, respectively. An intramolecular N-H?O inter-action occurs. Relatively weak inter-molecular C-H?O inter-actions between the ligands and the ClO(4) (-) ions result in a chain extending along the b axis.

SUBMITTER: Sarkar S 

PROVIDER: S-EPMC2983324 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature