Unknown

Dataset Information

0

4-(3-Carb-oxy-1-ethyl-6-fluoro-4-oxo-1,4-dihydro-7-quinol-yl)-1-methyl-piper-azin-ium picrate.

ABSTRACT: The pefloxacinium cation of the title salt, C(17)H(21)FN(3)O(3) (+)·C(6)H(2)N(3)O(7) (-), is composed of an essentially planar quinoline ring system [maximum deviation = 0.021?(2)?Å] and a piperazine ring, which adopts a chair conformation. In the picrate anion, the two O atoms of one of the o-NO(2) groups are disordered over two positions, with an occupancy ratio of 0.56?(4):0.44?(4). In the crystal structure, cations and anions are connected by inter-molecular N-H?O, O-H?O, C-H?O and C-H?F hydrogen bonds, forming a three-dimensional network. In addition, ?-? inter-actions between the pyridine rings and between the benzene rings of the anions, with centroid-centroid distances of 3.6103?(12) and 3.5298?(11)?Å, respectively, are observed.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC2983575 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

4-(3-Carb-oxy-1-ethyl-6-fluoro-4-oxo-1,4-dihydro-7-quinol-yl)-1-methyl-piper-azin-ium picrate.

Fun Hoong-Kun HK   Hemamalini Madhukar M   Shetty Divya N DN   Narayana B B   Yathirajan H S HS  

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3

The pefloxacinium cation of the title salt, C(17)H(21)FN(3)O(3) (+)·C(6)H(2)N(3)O(7) (-), is composed of an essentially planar quinoline ring system [maximum deviation = 0.021 (2) Å] and a piperazine ring, which adopts a chair conformation. In the picrate anion, the two O atoms of one of the o-NO(2) groups are disordered over two positions, with an occupancy ratio of 0.56 (4):0.44 (4). In the crystal structure, cations and anions are connected by inter-molecular N-H⋯O, O-H⋯O, C-H⋯O and C-H⋯F hyd  ...[more]

Similar Datasets

Unknown 5,7-Dimethyl-2,3-dihydro-1H-1,4-diazepin-4-ium picrate.
| S-EPMC2979234 | biostudies-literature
Unknown 4-(3-Carb-oxy-1-ethyl-6-fluoro-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium 4-carb-oxy-benzoate-benzene-1,4-dicarb-oxy-lic acid (2/1).
| S-EPMC3099834 | biostudies-other
Unknown Ethyl 7-chloro-1-cyclo-propyl-6-fluoro-8-nitro-4-oxo-1,4-dihydro-quinoline-3-carboxyl-ate.
| S-EPMC3414979 | biostudies-literature
Unknown catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro-quinoline-3-carboxyl-ato-?O,O)copper(II)]-?-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro-quinoline-3-carboxyl-ato-?N:O,O] tetra-hydrate].
| S-EPMC2960715 | biostudies-literature
Unknown 1-Ethyl-6-fluoro-7-(4-methyl-piperazin-4-ium-1-yl)-4-oxo-1,4-dihydroquinoline-3-carboxylate hexa-hydrate.
| S-EPMC2960169 | biostudies-literature
Unknown Ethyl 7-amino-1-cyclo-propyl-6-fluoro-8-meth-oxy-4-oxo-1,4-dihydro-quinoline-3-carboxyl-ate monohydrate.
| S-EPMC2960450 | biostudies-literature
Unknown Crystal structure of (RS)-4-(3-carb-oxy-1-ethyl-6,8-di-fluoro-4-oxo-1,4-di-hydro-quinolin-7-yl)-2-methyl-piperazin-1-ium 3-carb-oxy-5-fluoro-benzoate.
| S-EPMC6323884 | biostudies-other
Unknown Bis[8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydro-pyrido[2,3-d]pyrimidine-6-carb-oxy-lic acid] 2,5-dicarb-oxy-benzene-1,4-di-carboxyl-ate octa-hydrate.
| S-EPMC3099930 | biostudies-literature
Unknown (E)-5-(2-Chloro-phen-yl)-7-ethyl-2-oxo-2,3-dihydro-1H-thieno[2,3-e][1,4]diazepin-4-ium 2,4,6-trinitro-phenolate.
| S-EPMC3275259 | biostudies-literature
Unknown 4-(1-Cyclo-propyl-6-fluoro-4-oxo-1,4-dihydro-quinolin-7-yl)piperazin-1-ium 2,4,5-tricarb-oxy-benzene-1-carboxyl-ate monohydrate.
| S-EPMC3297959 | biostudies-literature