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N-(2,5-Dimethyl-phen-yl)-2-methyl-benzamide.

ABSTRACT: In the title compound, C(16)H(17)NO, the two aromatic rings are almost coplanar, making a dihedral angle of 1.9 (2)°. The amide group makes dihedral angles of 48.0 (3) and 48.6 (3)° with the 2-methyl-phenyl and the 2,5-dimethyl-phenyl rings, respectively. Inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains running along the a axis of the crystal.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2983932 | biostudies-literature |

REPOSITORIES: biostudies-literature

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N-(2,3-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title compound, C(16)H(17)NO, the two aromatic rings make a dihedral angle of 5.9?(2)°, while the central amide core -NH-C(=O)- is twisted by 44.0?(3) and 47.1?(3)° out of the planes of the 2,3-dimethyl-phenyl and 2-methyl-phenyl rings, respectively. In the crystal, N-H?O hydrogen bonds link the mol-ecules into infinite chains running along the b axis.

| S-EPMC3239120 | biostudies-literature

N-(2,6-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title mol-ecule, C(16)H(17)NO, the N-H and C=O groups are in the anti-periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl-phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3?(3) and 64.6?(3)° with the 2-methyl-phenyl and 2,6-dimethyl-phenyl rings, respectively, while the angle between the planes of the two rings is 14.26?(7)°. The mol-ecules are packed into chains via N-H?O hydrogen bonds. An intramolecular C-H?O hydrogen bond is also observed.

| S-EPMC2962217 | biostudies-literature

N-(2,4-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecule of the title compound, C(16)H(17)NO, the N-H and C=O bonds are anti to each other and the two benzene rings form a dihedral angle of 75.8?(1)°. The amide group is twisted by 28.1?(3) and 76.3?(2)° out of the planes of the 4-methyl-phenyl and 2,4-dimethyl-phenyl rings, respectively. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the c axis. The crystal studied was hemihedrally twinned with a twin law resulting from a twofold rotation about the a axis.

| S-EPMC2979239 | biostudies-literature

N-(3,4-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:The title compound, C(16)H(17)NO, crystallizes with two mol-ecules in the asymmetric unit. The conformation of the N-H bond is anti to the meta-methyl substituent in the aniline ring in the first mol-ecule and syn in the second mol-ecule. The dihedral angles between the two benzene rings are 52.6?(1) and 10.5?(1)° in the first and second mol-ecules, respectively. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the b axis of the crystal.

| S-EPMC2971027 | biostudies-literature

N-(2,6-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecular structure of the title compound, C(16)H(17)NO, the two aromatic rings are close to orthogonal to each other [dihedral angle 78.8?(1)°], while the central -NH-C(=O)- amide core is nearly coplanar with the benzoyl ring, forming a dihedral angle of 3.5?(2)°. Inter-molecular N-H?O hydrogen bonds in the crystal structure link the mol-ecules into infinite chains running along the c axis of the crystal, and a C-H?O interaction also occurs.

| S-EPMC2969511 | biostudies-literature

N-(2,4-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title compound, C(16)H(17)NO, the N-H bond is in an anti conformation with respect to the C=O bonds. The aniline and benzoyl rings are almost coplanar, making a dihedral angle of 4.9 (3)°. The plane of the amide group makes an angle of 61.3 (3)° with the aniline ring and 58.3 (3)° with the benzoyl ring. In the crystal, the mol-ecules are linked by N-H⋯O hydrogen bonds into chains running along the b axis.

| S-EPMC2969091 | biostudies-literature

N-[(2,4-Dimethyl-phen-yl)carbamothio-yl]-2-methyl-benzamide.

Project description:The title compound, C(17)H(18)N(2)OS, adopts a trans-cis geometry of the thio-urea group which is stabilized by intra-molecular hydrogen bonds between the O atom of the carbonyl group and the H atom of the thio-amide group. A C-H?S intramolecular hydrogen bond is also present. In the crystal structure, mol-ecules are linked by inter-molecular N-H?S hydrogen bonds to form centrosymmetric dimers.

| S-EPMC2961187 | biostudies-literature

N-(2,5-Dimethyl-phen-yl)-4-methyl-benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(15)H(17)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -61.0 (2)°. The dihedral angle between the two aromatic rings is 49.4 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

| S-EPMC2979993 | biostudies-literature

4-Chloro-N-(2,5-dimethyl-phen-yl)-2-methyl-benzene-sulfonamide.

Project description:The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains three independent moleules. The conformation of the N-H bonds are anti to the ortho-methyl groups of the sulfonyl benzene rings in all the mol-ecules. The sulfonyl and the aniline benzene rings are tilted relative to each other by 43.0?(2), 37.0?(2) and by 46.0?(1)° in the three mol-ecules. In the crystal, inter-molecular N-H?O hydrogen bonds link each of the mol-ecules into centrosymmetric dimers.

| S-EPMC3247308 | biostudies-literature

N-(3,4-Dimethyl-phen-yl)benzamide.

Project description:The conformation of the NH bond in the structure of the title compound (N34DMPBA), C(15)H(15)NO, is anti to the meta-methyl substituent in the aniline ring, similar to that observed with respect to the meta-chloro substituent in N-(3,4-dichloro-phen-yl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to the meta-methyl substituent in N-(3,4-dimethyl-phen-yl)acetamide. The bond parameters in N34DMPBA are similar to those in N34DCPBA and other benzanilides. The mol-ecules in N34DMPBA are packed into a column-like structure in the direction of the a axis through N-H?O hydrogen bonds.

| S-EPMC2915381 | biostudies-literature

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