Unknown

Dataset Information

0

Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothia-zin-10-yl)propan-2-aminium] tetrakis-(thio-cyanato-?N)cobaltate(II).

ABSTRACT: The asymmetric unit of the title salt, (C(16)H(20)N(3)S)(2)[Co(NCS)(4)], comprises one monovalent isothio-pendylium cation and one-half of a divalent thio-cyanatocobaltate(II) anion (2 symmetry). The central thia-zine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the mean plane of 0.272?(1) and 0.2852?(8)?Å for the N and S atoms. The mol-ecular structure of the cation is stabilized by an intra-molecular N-H?N hydrogen bond. Within the complex anion, the Co(II) atom is tetra-hedrally surrounded by four N atoms of the thio-cyanate ligands. ?-? stacking, with a distance of 3.7615?(10)?Å between the centroids of benzene and pyridine rings, helps to consolidate the packing.

SUBMITTER: Arunkashi HK 

PROVIDER: S-EPMC3006707 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothia-zin-10-yl)propan-2-aminium] tetrakis-(thio-cyanato-κN)cobaltate(II).

Arunkashi H K HK   Jeyaseelan S S   Vepuri Suresh Babu SB   Revanasiddappa H D HD   Devarajegowda H C HC  

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The asymmetric unit of the title salt, (C(16)H(20)N(3)S)(2)[Co(NCS)(4)], comprises one monovalent isothio-pendylium cation and one-half of a divalent thio-cyanatocobaltate(II) anion (2 symmetry). The central thia-zine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the mean plane of 0.272 (1) and 0.2852 (8) Å for the N and S atoms. The mol-ecular structure of the cation is stabilized by an intra-molecular N-H⋯N hydrogen bond. Within the complex anion, t  ...[more]

Similar Datasets

Unknown Bis(benzo-15-crown-5-?O)barium tetrakis-(isothio-cyanato-?N)cobaltate(II).
| S-EPMC2980073 | biostudies-literature
Unknown 3-[4-(10H-Indolo[3,2-b]quinolin-11-yl)piperazin-1-yl]propan-1-ol.
| S-EPMC3239093 | biostudies-literature
Unknown 2,3-Diphenyl-2,3-di-hydro-4H-pyrido[3,2-e][1,3]thia-zin-4-one.
| S-EPMC4051078 | biostudies-other
Unknown 1-(10H-Phenothia-zin-2-yl)ethanone.
| S-EPMC3051484 | biostudies-literature
Unknown 1-(10H-phenothia-zin-10-yl)ethanone.
| S-EPMC3588965 | biostudies-literature
Unknown 1-(5,5-Dioxido-10H-phenothia-zin-10-yl)ethanone.
| S-EPMC3151987 | biostudies-literature
Unknown Crystal structures of two solvated 2-aryl-3-phenyl-2,3-di-hydro-4H-pyrido[3,2-e][1,3]thia-zin-4-ones.
| S-EPMC6829726 | biostudies-literature
Unknown 5-Benzyl-5H-pyrido[3,2-b]indole.
| S-EPMC3200621 | biostudies-literature
Unknown 10-(1,3-Benzothia-zol-2-yl)-1,1,7,7-tetra-methyl-2,3,6,7-tetra-hydro-1H,5H,11H-pyrano[3,2-g]pyrido[3,2,1-hi]quinoline.
| S-EPMC2983933 | biostudies-literature
Unknown 2-Benzoyl-2H-1,4-benzothia-zin-3(4H)-one.
| S-EPMC3007413 | biostudies-literature