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5-Benzyl-5H-pyrido[3,2-b]indole.

ABSTRACT: The title compound, C(18)H(14)N(2), was prepared by twofold Pd-catalyzed aryl-amination of a cyclic pyrido-benzo-iodo-lium salt. In the crystal, two mol-ecules of 9-benzyl-?-carboline form centrosymmetrical dimers with distances of 3.651?(2)?Å between the centroids of the pyridine rings and 3.961?(2)?Å between the centroids of the pyrrole and pyridine rings. The phenyl rings point to the other mol-ecule in the dimer and the carboline core is essentially planar [maximum deviation of 0.027?(2)?Å].

SUBMITTER: Letessier J

PROVIDER: S-EPMC3200621 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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5-Benzyl-5H-pyrido[3,2-b]indole.

Letessier Julien J Schollmeyer Dieter D Detert Heiner H

Acta crystallographica. Section E, Structure reports online 20110817 Pt 9

The title compound, C(18)H(14)N(2), was prepared by twofold Pd-catalyzed aryl-amination of a cyclic pyrido-benzo-iodo-lium salt. In the crystal, two mol-ecules of 9-benzyl-δ-carboline form centrosymmetrical dimers with distances of 3.651 (2) Å between the centroids of the pyridine rings and 3.961 (2) Å between the centroids of the pyrrole and pyridine rings. The phenyl rings point to the other mol-ecule in the dimer and the carboline core is essentially planar [maximum deviation of 0.027 (2) Å]. ...[more]

PMID: 22058962

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