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5-Benzyl-5H-pyrido[3,2-b]indole.

ABSTRACT: The title compound, C(18)H(14)N(2), was prepared by twofold Pd-catalyzed aryl-amination of a cyclic pyrido-benzo-iodo-lium salt. In the crystal, two mol-ecules of 9-benzyl-δ-carboline form centrosymmetrical dimers with distances of 3.651 (2) Å between the centroids of the pyridine rings and 3.961 (2) Å between the centroids of the pyrrole and pyridine rings. The phenyl rings point to the other mol-ecule in the dimer and the carboline core is essentially planar [maximum deviation of 0.027 (2) Å].

SUBMITTER: Letessier J

PROVIDER: S-EPMC3200621 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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5-Benzyl-5H-pyrido[3,2-b]indole.

Letessier Julien J Schollmeyer Dieter D Detert Heiner H

Acta crystallographica. Section E, Structure reports online 20110817 Pt 9

The title compound, C(18)H(14)N(2), was prepared by twofold Pd-catalyzed aryl-amination of a cyclic pyrido-benzo-iodo-lium salt. In the crystal, two mol-ecules of 9-benzyl-δ-carboline form centrosymmetrical dimers with distances of 3.651 (2) Å between the centroids of the pyridine rings and 3.961 (2) Å between the centroids of the pyrrole and pyridine rings. The phenyl rings point to the other mol-ecule in the dimer and the carboline core is essentially planar [maximum deviation of 0.027 (2) Å]. ...[more]

PMID: 22058962

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