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1-Cyano-meth-yl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-bromidocuprate(II).

ABSTRACT: In the crystal structure of the title complex, (C(8)H(15)N(3))[CuBr(4)], the Cu atom is coordinated by four bromido ligands within a strongly distorted tetra-hedron. The anions and cations are connected by weak N-H⋯Br and C-H⋯Br hydrogen-bonding inter-actions.

SUBMITTER: Cai Y

PROVIDER: S-EPMC3006955 | biostudies-literature |

REPOSITORIES: biostudies-literature

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1,4-Diazo-niabicyclo-[2.2.2]octane tetra-bromidocuprate(II) monohydrate.

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Project description:In the crystal structure of the title compound, (C(8)H(15)N(3))[CuCl(4)], the cations and anions, in which the Cu(II) atom is tetra-hedrally coordinated, are linked via N-H?Cl hydrogen bonds into chains that are elongated in the c-axis direction.

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Project description:In the title compound, C(6)H(14)N(2+)·C(8)H(4)O(4) (2-), the protonated 1,4-diazo-niabicyclo-[2.2.2]octane cations and the deprotonated terephthalate anions are alternately linked by N-H?O hydrogen bonds into chains.

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