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1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocobaltate(II).

ABSTRACT: In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetra-hedral geometry. In the crystal, N-H?Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C-H?Cl and C-H?N inter-actions.

SUBMITTER: Zhang Y

PROVIDER: S-EPMC3344387 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocobaltate(II).

Zhang Yi Y Zhu Bo-Han BH

Acta crystallographica. Section E, Structure reports online 20120425 Pt 5

In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetra-hedral geometry. In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C-H⋯Cl and C-H⋯N inter-actions. ...[more]

PMID: 22590149

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