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1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

ABSTRACT: In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H?Cl hydrogen bonds, forming chains parallel to [001]. C-H?Cl inter-actions also occur.

SUBMITTER: Zhang Y

PROVIDER: S-EPMC3344406 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

Zhang Yi Y Zhu Bo Han BH

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001]. C-H⋯Cl inter-actions also occur. ...[more]

PMID: 22590168

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