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1-Benzyl-3-[(trimethyl-sil-yl)meth-yl]benzimidazolium chloride monohydrate.

ABSTRACT: The title compound, C(18)H(23)N(2)Si(+)·Cl(-)·H(2)O, was synthesized from 1-[(trimethyl-sil-yl)meth-yl]benzimidazole and benzyl chloride in dimethyl-formamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022?(2)?Å, and makes an angle of 74.80?(12)° with the phenyl ring. The crystal packing is stabilized by O-H?Cl, C-H?Cl, C-H?O and C-H?? inter-actions between symmetry-related mol-ecules together with ?-? stacking inter-actions between the imidazolium and benzene rings [centroid-centroid distance = 3.5690?(15)?Å] and between the benzene rings [centroid-centroid distance = 3.7223?(14)?Å].

SUBMITTER: Akkurt M 

PROVIDER: S-EPMC3007035 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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1-Benzyl-3-[(trimethyl-sil-yl)meth-yl]benzimidazolium chloride monohydrate.

Akkurt Mehmet M   Celik Ismail I   Küçükbay Hasan H   Sireci Nihat N   Büyükgüngör Orhan O  

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

The title compound, C(18)H(23)N(2)Si(+)·Cl(-)·H(2)O, was synthesized from 1-[(trimethyl-sil-yl)meth-yl]benzimidazole and benzyl chloride in dimethyl-formamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the phenyl ring. The crystal packing is stabilized by O-H⋯Cl, C-H⋯Cl, C-H⋯O and C-H⋯π inter-actions between symmetry-related mol-ecules together with π-π stacking inter-actions between the imidazolium and  ...[more]

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