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4-Fluoro-anilinium tetra-chloridoferrate(III) 18-crown-6 clathrate.

ABSTRACT: The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH(3) (+) substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether mol-ecules result in a rotator-stator-like structure.

SUBMITTER: Ge JZ

PROVIDER: S-EPMC3006967 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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4-Fluoro-anilinium tetra-chloridoferrate(III) 18-crown-6 clathrate.

Ge Jia-Zhen JZ Zhao Min-Min MM

Acta crystallographica. Section E, Structure reports online 20100605 Pt 7

The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH(3) (+) substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether mol-ecules result in a rotator-stator-like structure. ...[more]

PMID: 21587679

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