Ontology highlight
ABSTRACT:
SUBMITTER: Back AD
PROVIDER: S-EPMC3007074 | biostudies-literature | 2010 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100609 Pt 7
The noteworthy structural feature of the title complex, poly[acetonitrile-tetra-μ(2)-thio-cyanato-barium(II)digold(I)], {[Au(2)Ba(SCN)(4)(CH(3)CN)]}(n), is that the bis-(thio-cyanato)-aurate(I) anion adopts both monomeric and trimeric motifs. The trimer unit has an Au⋯Au distance of 3.1687 (3) Å. In both the monomeric and trimeric units, the Au(I) atoms are also bonded to two S atoms. Within the trimeric unit, the Au(I) atoms exist in differing environments; one Au atom has a T-shaped three-coor ...[more]