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{Ba[Au(SCN)(2)](2)}(n): a three-dimensional net comprised of monomeric and trimeric gold(I) units.

ABSTRACT: The noteworthy structural feature of the title complex, poly[acetonitrile-tetra-?(2)-thio-cyanato-barium(II)digold(I)], {[Au(2)Ba(SCN)(4)(CH(3)CN)]}(n), is that the bis-(thio-cyanato)-aurate(I) anion adopts both monomeric and trimeric motifs. The trimer unit has an Au?Au distance of 3.1687?(3)?Å. In both the monomeric and trimeric units, the Au(I) atoms are also bonded to two S atoms. Within the trimeric unit, the Au(I) atoms exist in differing environments; one Au atom has a T-shaped three-coordinate geometry while the other has a square-planar four-coordinate geometry. The Au(I) atom of the monomer adopts a linear two-coordinate geometry. The extended structure can be described as a three-dimensional coordination polymer consisting of chains of Ba atoms bridged by thio-cyanate N atoms. These chains are cross-linked via the gold monomeric and trimeric units.

SUBMITTER: Back AD

PROVIDER: S-EPMC3007074 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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{Ba[Au(SCN)(2)](2)}(n): a three-dimensional net comprised of monomeric and trimeric gold(I) units.

Back A Darren AD Stroud Tonia L TL Schroll Cynthia A CA Coker Nathan L NL Krause Jeanette A JA

Acta crystallographica. Section E, Structure reports online 20100609 Pt 7

The noteworthy structural feature of the title complex, poly[acetonitrile-tetra-μ(2)-thio-cyanato-barium(II)digold(I)], {[Au(2)Ba(SCN)(4)(CH(3)CN)]}(n), is that the bis-(thio-cyanato)-aurate(I) anion adopts both monomeric and trimeric motifs. The trimer unit has an Au⋯Au distance of 3.1687 (3) Å. In both the monomeric and trimeric units, the Au(I) atoms are also bonded to two S atoms. Within the trimeric unit, the Au(I) atoms exist in differing environments; one Au atom has a T-shaped three-coor ...[more]

PMID: 21587698

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