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8-Bromo-1,3-diphenyl-2,3-dihydro-1H-naphtho-[1,2-e][1,3]oxazine.

ABSTRACT: The title compound, C(24)H(18)BrNO, consists of an envelope-configured oxazine ring with a fused 8-bromo-1,3-diphenyl group and two bonded phenyl rings. The dihedral angles between the mean planes of the 8-bromo-1,3-diphenyl and the phenyl rings are 54.5?(6) and 87.4?(8)°, respectively. The oxazine is essentially coplanar with the 8-bromo-1,3-diphenyl [dihedral angle = 9.4?(1)°]. Weak C-H?? inter-actions contribute to the crystal packing.

SUBMITTER: Jasinski JP 

PROVIDER: S-EPMC3007280 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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8-Bromo-1,3-diphenyl-2,3-dihydro-1H-naphtho-[1,2-e][1,3]oxazine.

Jasinski Jerry P JP   Pek Albert E AE   Mayekar A N AN   Yathirajan H S HS   Narayana B B  

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

The title compound, C(24)H(18)BrNO, consists of an envelope-configured oxazine ring with a fused 8-bromo-1,3-diphenyl group and two bonded phenyl rings. The dihedral angles between the mean planes of the 8-bromo-1,3-diphenyl and the phenyl rings are 54.5 (6) and 87.4 (8)°, respectively. The oxazine is essentially coplanar with the 8-bromo-1,3-diphenyl [dihedral angle = 9.4 (1)°]. Weak C-H⋯π inter-actions contribute to the crystal packing. ...[more]

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