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Diaqua-bis-(seleno-cyanato-?N)bis-(pyrimidine-?N)manganese(II).

ABSTRACT: In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded seleno-cyanate anions and two O-bonded water mol-ecules in a distorted octa-hedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one seleno-cyanate anion, one water mol-ecule and one pyrimidine ligand in general positions. The crystal structure consists of discrete building blocks of composition [Mn(NCSe)(2)(pyrimidine)(2)(H(2)O)(2)], which are connected into layers parallel to (101) by strong water-pyrimidine O-H?N hydrogen bonds.

SUBMITTER: Wriedt M 

PROVIDER: S-EPMC3007293 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Diaqua-bis-(seleno-cyanato-κN)bis-(pyrimidine-κN)manganese(II).

Wriedt Mario M   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded seleno-cyanate anions and two O-bonded water mol-ecules in a distorted octa-hedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one seleno-cyanate anion, one water mol-ecule and one pyrimidine ligand in general positions. The crystal structure  ...[more]

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